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2020年度


31694003 

△Advanced Physical Chemistry(E)
Advanced Physical Chemistry (E)
2単位/Unit  秋学期/Fall  京田辺/Kyotanabe  講義/Lecture

  塩井 章久

<概要/Course Content Summary>

This subject deals with chemical thermodynamics,focusing on the basic concepts and their applications to mainly gas and liquid. Phase and chemical equilibria are treated on the basis of the first and the second laws of thermodynamics. Thermodynamic quantities and their relationships are introduced as if students found them from experimental results and their own thinking. The physical meanings of chemical potential are explained in detail.

<到達目標/Goals,Aims>

To understand physical implications of the first and the second laws of thermodynamics 
To understand chemical potential correctly 
To calculate thermodynamic quantities of gas and liquid 
To calculate thermodynamic quantities regarding phase and chemical equilibria  
To understand chemical potential in a field

<授業計画/Schedule>

(実施回/
Week)
(内容/
Contents)
(授業時間外の学習/
Assignments)
(実施回/ Week) (内容/ Contents) energy transformation -the maximum work-  (授業時間外の学習/ Assignments) review the lecture note and text on the day 
(実施回/ Week) (内容/ Contents) What is the irreversible and reversible change?  (授業時間外の学習/ Assignments) review the lecture note and text on the day 
(実施回/ Week) (内容/ Contents) Carnot's theorem  (授業時間外の学習/ Assignments) review the lecture note and text on the day 
(実施回/ Week) (内容/ Contents) absolute temperature and entropy  (授業時間外の学習/ Assignments) review the lecture note and text on the day 
(実施回/ Week) (内容/ Contents) thermodynamic potential  (授業時間外の学習/ Assignments) review the lecture note and text on the day 
(実施回/ Week) (内容/ Contents) chemical potential  (授業時間外の学習/ Assignments) review the lecture note and text on the day 
(実施回/ Week) (内容/ Contents) What is the driving force of chemical reaction?  (授業時間外の学習/ Assignments) review the lecture note and text on the day 
(実施回/ Week) (内容/ Contents) thermodynamics of gas, liquid and solid  (授業時間外の学習/ Assignments) review the lecture note and text on the day 
(実施回/ Week) (内容/ Contents) phase changes  (授業時間外の学習/ Assignments) review the lecture note and text on the day 
(実施回/ Week) 10  (内容/ Contents) theory of mixtures -partial molar qnatities-  (授業時間外の学習/ Assignments) review the lecture note and text on the day 
(実施回/ Week) 11  (内容/ Contents) colligative properties  (授業時間外の学習/ Assignments) review the lecture note and text on the day 
(実施回/ Week) 12  (内容/ Contents) chemical equilibrium  (授業時間外の学習/ Assignments) review the lecture note and text on the day 
(実施回/ Week) 13  (内容/ Contents) chemical equilibrium under an external field  (授業時間外の学習/ Assignments) review the lecture note and text on the day 
(実施回/ Week) 14  (内容/ Contents) electrode potential  (授業時間外の学習/ Assignments) review the lecture note and text on the day 
(実施回/ Week) 15  (内容/ Contents) radiation  (授業時間外の学習/ Assignments) preparation 

The assignment of the above contents to each week may fluctuate. Nevertheless, the whole contents are kept throughout the course.

<成績評価基準/Evaluation Criteria>

several times exercises (reports) presented in class  20%  homework to be done 
examination  80%  thorough understanding of lecture 

Correct understanding of thermodynamics containing mathematical treatments is necessary.

<参考文献/Reference Book>

Dilip Kondepudi and Ilya Prigogine  『Modern Thermodynamics-from heat engines to dissipative structures-』(John Wiley and Sons Ltd.、2007)ISBN:978-0471-97393-5 
 

 

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